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  2. Cyanometalate - Wikipedia

    en.wikipedia.org/wiki/Cyanometalate

    Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. [1] Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions.

  3. Coordination complex - Wikipedia

    en.wikipedia.org/wiki/Coordination_complex

    Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...

  4. Coordination number - Wikipedia

    en.wikipedia.org/wiki/Coordination_number

    In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion/molecule/atom is called a ligand .

  5. Transition metal carbonate and bicarbonate complexes

    en.wikipedia.org/wiki/Transition_metal_carbonate...

    With a saturated pi-system, it has no pi-acceptor properties. With multiple electronegative elements, it is not strongly basic. The latter is consistent with the pK a ’s of carbonic acid: pK 1 = 6.77 and pK 2 = 9.93. To a single metal ion, carbonate is observed to bind in both unidentate (κ 1-) and bidentate (κ 2-) fashions. [5]

  6. Coordination geometry - Wikipedia

    en.wikipedia.org/wiki/Coordination_geometry

    The number of coordination bonds (coordination number) can vary from two in K[Ag(CN) 2] as high as 20 in Th(η 5-C 5 H 5) 4. [ 2 ] One of the most common coordination geometries is octahedral , where six ligands are coordinated to the metal in a symmetrical distribution, leading to the formation of an octahedron if lines were drawn between the ...

  7. Ligand - Wikipedia

    en.wikipedia.org/wiki/Ligand

    In coordination chemistry, a ligand [a] is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs , often through Lewis bases . [ 1 ]

  8. Coordinate covalent bond - Wikipedia

    en.wikipedia.org/wiki/Coordinate_covalent_bond

    In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond [3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]

  9. Metal amides - Wikipedia

    en.wikipedia.org/wiki/Metal_amides

    Metal amides (systematic name metal azanides) are a class of coordination compounds composed of a metal center with amide ligands of the form NR 2 −. Amido complexes of the parent amido ligand NH 2 − are rare compared to complexes with diorganylamido ligand, such as dimethylamido. Amide ligands have two electron pairs available for bonding.