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The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
In thermal engineering, the logarithmic mean temperature difference (LMTD) is used to determine the temperature driving force for heat transfer in flow systems, most notably in heat exchangers. The LMTD is a logarithmic average of the temperature difference between the hot and cold feeds at each end of the double pipe exchanger.
Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer P = / W ML 2 T −3: Thermal intensity I = / W⋅m −2
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.
Flux F through a surface, dS is the differential vector area element, n is the unit normal to the surface. Left: No flux passes in the surface, the maximum amount flows normal to the surface.
Engine power is the power that an engine can put out. It can be expressed in power units, most commonly kilowatt, pferdestärke (metric horsepower), or horsepower.In terms of internal combustion engines, the engine power usually describes the rated power, which is a power output that the engine can maintain over a long period of time according to a certain testing method, for example ISO 1585.
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Temperature vs. heat load diagram of hot stream (H 2 O entering at 20 bar, 473.15 K, and 4 kg/s) and cold stream (R-11 entering at 18 bar, 303.15 K, and 5 kg/s) in a counter-flow heat exchanger. "Pinch" is the point of closest approach between the hot and cold streams in the T vs. H diagram.