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Benzotrichloride is a poorly water-soluble, clear to yellowish liquid with a penetrating odor. It hydrolyzes rapidly to benzoic acid and hydrochloric acid with a half life of about 2.4 minutes, thus making the compound unstable in the presence of water. [2]
This is accomplished by the Gattermann-Koch reaction, accomplished by treating benzene with carbon monoxide and hydrogen chloride under high pressure, catalyzed by a mixture of aluminium chloride and cuprous chloride. Simple ketones that could be obtained by Friedel–Crafts acylation are produced by alternative methods, e.g., oxidation, in ...
A few types of aromatic compounds, such as phenol, will react without a catalyst, but for typical benzene derivatives with less reactive substrates, a Lewis acid is required as a catalyst. Typical Lewis acid catalysts include AlCl 3, FeCl 3, FeBr 3 and ZnCl 2. These work by forming a highly electrophilic complex which is attacked by the benzene ...
tert-Butylbenzene can be produced by the treatment of benzene with isobutene [1] or by the reaction of benzene with tert-butyl chloride in presence of anhydrous aluminium chloride, [2] the latter is depicted below:
2 Al + 3 Cl 2 → 2 AlCl 3 2 Al + 6 HCl → 2 AlCl 3 + 3 H 2. Aluminium chloride may be formed via a single displacement reaction between copper(II) chloride and aluminium. 2 Al + 3 CuCl 2 → 2 AlCl 3 + 3 Cu. In the US in 1993, approximately 21,000 tons were produced, not counting the amounts consumed in the production of aluminium. [7]
In the presence of aluminium chloride (AlCl 3), S 2 Cl 2 reacts with benzene to give diphenyl sulfide: 8 S 2 Cl 2 + 16 C 6 H 6 → 8 (C 6 H 5 ) 2 S + 16 HCl + S 8 Anilines (1) react with S 2 Cl 2 in the presence of NaOH to give 1,2,3-benzodithiazolium chloride (2) ( Herz reaction ) which can be transformed into ortho -aminothiophenolates (3 ...
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In 1867, Henry Bassett proved that the compound produced from benzene and antimony was the same as Julian's carbon chloride and named it "hexachlorobenzene". [ 10 ] [ 9 ] Leopold Gmelin named it "dichloride of carbon" and claimed that the carbon was derived from cast iron and the chlorine was from crude saltpetre .