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In thermodynamics, an isochoric process, also called a constant-volume process, an isovolumetric process, or an isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains constant. An isochoric process is exemplified by the heating or the cooling of the contents of a sealed ...
Chemical potential / Particle number; ... Isochoric : The process is constant volume ... The Otto Cycle is an example of a reversible thermodynamic cycle.
A polytropic process is a thermodynamic process that obeys the relation: = where p is the pressure , V is volume , n is the polytropic index , and C is a constant. The polytropic process equation describes expansion and compression processes which include heat transfer.
In the example, a cycle consisting of four quasi-static processes is shown. Each process has a well-defined start and end point in the pressure-volume state space. In this particular example, processes 1 and 3 are isothermal, whereas processes 2 and 4 are isochoric.
Another important kind of work is isochoric work, i.e., work that involves no eventual overall change of volume of the system between the initial and the final states of the process. Examples are friction on the surface of the system as in Rumford's experiment; shaft work such as in Joule's experiments; stirring of the system by a magnetic ...
The law was named after scientist Jacques Charles, who formulated the original law in his unpublished work from the 1780s.. In two of a series of four essays presented between 2 and 30 October 1801, [2] John Dalton demonstrated by experiment that all the gases and vapours that he studied expanded by the same amount between two fixed points of temperature.
Therefore, an isobaric process can be more succinctly described as =. Enthalpy and isochoric specific heat capacity are very useful mathematical constructs, since when analyzing a process in an open system, the situation of zero work occurs when the fluid flows at constant pressure. In an open system, enthalpy is the quantity which is useful to ...
Throughout an entire reversible process, the system is in thermodynamic equilibrium, both physical and chemical, and nearly in pressure and temperature equilibrium with its surroundings. This prevents unbalanced forces and acceleration of moving system boundaries, which in turn avoids friction and other dissipation.