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They may depend on the partial pressure of the products and reactants, but if the number of moles of gaseous reactants is equal to the number of moles of gaseous products, pressure has no effect on equilibrium. Changing total pressure by adding an inert gas at constant volume does not affect the equilibrium concentrations (see § Effect of ...
Equilibrium vapor pressure does not require the condensed phase to be a flat surface; it might consist of tiny droplets possibly containing solutes (impurities), such as a cloud. [ 19 ] [ 18 ] Equilibrium vapor pressure may differ significantly from saturation vapor pressure depending on the size of droplets and presence of other particles ...
The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...
The equilibrium concentration of each component in the liquid phase is often different from its concentration (or vapor pressure) in the vapor phase, but there is a relationship. The VLE concentration data can be determined experimentally or approximated with the help of theories such as Raoult's law , Dalton's law , and Henry's law .
Fluid statics or hydrostatics is the branch of fluid mechanics that studies fluids at hydrostatic equilibrium [1] and "the pressure in a fluid or exerted by a fluid on an immersed body". [ 2 ] It encompasses the study of the conditions under which fluids are at rest in stable equilibrium as opposed to fluid dynamics , the study of fluids in motion.
Pressure dependence of the water ionization constant at 25 °C. In general, ionization in aqueous solutions tends to increase with increasing pressure. In a condensed phase, the pressure dependence of the equilibrium constant is associated with the reaction volume. [18] For reaction: α A + β B ⇌ σ S + τ T. the reaction volume is:
The vapor pressure of water is the pressure exerted by molecules of water vapor in gaseous form (whether pure or in a mixture with other gases such as air). The saturation vapor pressure is the pressure at which water vapor is in thermodynamic equilibrium with its condensed state .
Diagram of a newly formed planet in a state of hydrostatic equilibrium. In fluid mechanics, hydrostatic equilibrium (hydrostatic balance, hydrostasy) is the condition of a fluid or plastic solid at rest, which occurs when external forces, such as gravity, are balanced by a pressure-gradient force. [1]