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  2. 2-Chlorobutane - Wikipedia

    en.wikipedia.org/wiki/2-Chlorobutane

    Being an alkyl chloride, its boiling point varies depending on what kind of halide is attached and where it is attached. The boiling points of chlorides are lower than bromides or iodides due to the small size of chlorine relative to other halogens, and its weaker intermolecular forces.

  3. Haloalkane - Wikipedia

    en.wikipedia.org/wiki/Haloalkane

    Haloalkane or alkyl halides are the compounds which have the general formula "RX" where R is an alkyl or substituted alkyl group and X is a halogen (F, Cl, Br, I). Haloalkanes have been known for centuries. Chloroethane was produced in the 15th century. The systematic synthesis of such compounds developed in the 19th century in step with the ...

  4. Halogen bond - Wikipedia

    en.wikipedia.org/wiki/Halogen_bond

    A halogen bond is almost collinear with the halogen atom's other, conventional bond, but the geometry of the electron-charge donor may be much more complex.. Multi-electron donors such as ethers and amines prefer halogen bonds collinear with the lone pair and donor nucleus.

  5. Intermolecular force - Wikipedia

    en.wikipedia.org/wiki/Intermolecular_force

    The attractive force draws molecules closer together and gives a real gas a tendency to occupy a smaller volume than an ideal gas. Which interaction is more important depends on temperature and pressure (see compressibility factor). In a gas, the distances between molecules are generally large, so intermolecular forces have only a small effect.

  6. Alkyl group - Wikipedia

    en.wikipedia.org/wiki/Alkyl_group

    Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl. The formula of alkyl radicals are the same as alkyl groups, except the free valence "−" is replaced by the dot "•" and adding "radical" to the name of the alkyl group (e.g. methyl radical •CH 3).

  7. Molecular dynamics - Wikipedia

    en.wikipedia.org/wiki/Molecular_dynamics

    Forces are then applied to specific atoms at either a constant velocity or a constant force. Umbrella sampling is used to move the system along the desired reaction coordinate by varying, for example, the forces, distances, and angles manipulated in the simulation. Through umbrella sampling, all of the system's configurations—both high-energy ...

  8. Halocarbon - Wikipedia

    en.wikipedia.org/wiki/Halocarbon

    Halocarbon compounds are chemical compounds in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms (fluorine, chlorine, bromine or iodine – group 17) resulting in the formation of organofluorine compounds, organochlorine compounds, organobromine compounds, and organoiodine compounds.

  9. Alcohol (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Alcohol_(chemistry)

    In other less formal contexts, an alcohol is often called with the name of the corresponding alkyl group followed by the word "alcohol", e.g., methyl alcohol, ethyl alcohol. Propyl alcohol may be n-propyl alcohol or isopropyl alcohol, depending on whether the hydroxyl group is bonded to the end or middle carbon on the straight propane chain. As ...