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The table above gives properties of the vapor–liquid equilibrium of anhydrous ammonia at various temperatures. The second column is vapor pressure in k Pa . The third column is the density of the liquid phase.
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Gas N 2: 0 Ammonia (ammonium hydroxide) Aqueous NH 3 (NH 4 OH) −80.8 Ammonia: Gas NH 3: −46.1 Ammonium nitrate: Solid NH 4 NO 3: −365.6 Ammonium chloride: Solid NH 4 Cl −314.55 Nitrogen dioxide: Gas NO 2: 33.2 Hydrazine: Gas N 2 H 4: 95.4 Hydrazine: Liquid N 2 H 4: 50.6 Nitrous oxide: Gas N 2 O 82.05 Nitric oxide: Gas NO 90.29 ...
The hydrogen in ammonia is susceptible to replacement by a myriad substituents. Ammonia gas reacts with metallic sodium to give sodamide, NaNH 2. [38] With chlorine, monochloramine is formed. Pentavalent ammonia is known as λ 5-amine, nitrogen pentahydride decomposes spontaneously into trivalent ammonia (λ 3-amine) and hydrogen gas at normal ...
Thermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy.Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles.
By convention, the (higher) heat of combustion is defined to be the heat released for the complete combustion of a compound in its standard state to form stable products in their standard states: hydrogen is converted to water (in its liquid state), carbon is converted to carbon dioxide gas, and nitrogen is converted to nitrogen gas. That is ...
The equilibrium, between the gas as a separate phase and the gas in solution, will by Le Châtelier's principle shift to favour the gas going into solution as the temperature is decreased (decreasing the temperature increases the solubility of a gas). When a saturated solution of a gas is heated, gas comes out of the solution.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds