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A molecular sieve is a material with pores (voids or holes), having uniform size comparable to that of individual molecules, linking the interior of the solid to its exterior. These materials embody the molecular sieve effect , the preferential sieving of molecules larger than the pores.
Size-exclusion chromatography, also known as molecular sieve chromatography, [1] is a chromatographic method in which molecules in solution are separated by their shape, and in some cases size. [2] It is usually applied to large molecules or macromolecular complexes such as proteins and industrial polymers . [ 3 ]
With this variant of PSA developed for use in laboratory nitrogen generators, nitrogen gas is produced into two steps: in the first step, the compressed air is forced to pass through a carbon molecular sieve to produce nitrogen at a purity of approximately 98%; in the second step this nitrogen is forced to pass into a second carbon molecular ...
A sieve analysis (or gradation test) is a practice or procedure used in geology, civil engineering, [1] and chemical engineering [2] to assess the particle size distribution (also called gradation) of a granular material by allowing the material to pass through a series of sieves of progressively smaller mesh size and weighing the amount of material that is stopped by each sieve as a fraction ...
Pentasil-zeolites are defined by their structure type, and more specifically by their X-ray diffraction patterns. ZSM -5 is the trade name of a pentasil-zeolite. As early as 1967, Argauer and Landolt worked out parameters for the synthesis of pentasilzeolites, particularly those relating to the following molar ratios: OH − /SiO 2 = 0.07–10, SiO 2 /Al 2 O 3 = 5–100, H 2 O/SiO 2 = 1–240. [1]
Calculation of molecular mass by static light scattering measurement using Debye plot [7] If the measured particles are smaller than λ/20, the form factor P(θ) can be neglected (P(θ)→1). Therefore, the Zimm equation is simplified to the Debye equation, as follows:
In mass transfer, the sieving coefficient is a measure of equilibration between the concentrations of two mass transfer streams. It is defined as the mean pre- and post-contact concentration of the mass receiving stream divided by the pre- and post-contact concentration of the mass donating stream.
The total volume can be considered by the following equation, where V g is the volume of the polymer gel and V t is the total volume: [5] = + + As can be inferred, there is a limited range of molecular weights that can be separated by each column, therefore the size of the pores for the packing should be chosen according to the range of ...