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Diethylaminosulfur trifluoride (DAST) is the organosulfur compound with the formula Et 2 NSF 3. This liquid is a fluorinating reagent used for the synthesis of organofluorine compounds . [ 1 ] The compound is colourless; older samples assume an orange colour.
Fluorination with aminosulfuranes is a chemical reaction that transforms oxidized organic compounds into organofluorine compounds.Aminosulfuranes selectively exchange hydroxyl groups for fluorine, but are also capable of converting carbonyl groups, halides, silyl ethers, and other functionality into organofluorides.
Ferric nitrate has no large scale applications. It is a catalyst for the synthesis of sodium amide from a solution of sodium in ammonia: [10] 2 NH 3 + 2Na → 2 NaNH 2 + H 2. Certain clays impregnated with ferric nitrate have been shown to be useful oxidants in organic synthesis.
Industrial production of sodium nitrite follows one of two processes, the reduction of nitrate salts, or the oxidation of lower nitrogen oxides. One method uses molten sodium nitrate as the salt, and lead which is oxidized, while a more modern method uses scrap iron filings to reduce the nitrate. [4] [88] NaNO 3 + Pb → NaNO 2 + PbO
The cycle begins with reduction of an iron-nitrite complex to a metal nitrosyl complex. [3] The copper-containing enzyme nitrite reductase (CuNIR) catalyzes the 1-electron reduction of nitrite to nitric oxide. The proposed mechanism entails the protonation of a κ 2O,O-NO 2-Cu(I) complex.
Iron has five nitrides observed at ambient conditions, Fe 2 N, Fe 3 N 4, Fe 4 N, Fe 7 N 3 and Fe 16 N 2.They are crystalline, metallic solids. Group 7 and group 8 transition metals form nitrides that decompose at relatively low temperatures—iron nitride, Fe 2 N decomposes with loss of molecular nitrogen at around 400 °C and formation of lower-nitrogen content iron nitrides.
Iron and ligand are absorbed separately by the plant roots whereby the highly stable ferric chelate is first reduced to the less stable ferrous chelate. [6] In horticulture , iron chelate is often referred to as 'sequestered iron' and is used as a plant tonic, often mixed with other nutrients and plant foods (e.g. seaweed ).
Being the conjugate base of a strong acid (nitric acid, pK a = -1.4), nitrate has modest Lewis basicity.Two coordination modes are common: unidentate and bidentate.Often, bidentate nitrate, denoted κ 2-NO 3, is bound unsymmetrically in the sense that one M-O distance is clearly bonding and the other is more weakly interacting. [2]