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Diethylaminosulfur trifluoride (DAST) is the organosulfur compound with the formula Et 2 NSF 3. This liquid is a fluorinating reagent used for the synthesis of organofluorine compounds . [ 1 ] The compound is colourless; older samples assume an orange colour.
Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO 3) 3. (H 2 O) n. Most common is the nonahydrate Fe(NO 3) 3. (H 2 O) 9. The hydrates are all pale colored, water-soluble paramagnetic salts.
Zinc nitrate has no large scale application but is used on a laboratory scale for the synthesis of coordination polymers. [4] Its controlled decomposition to zinc oxide has also been used for the generation of various ZnO based structures, including nanowires. [5] It can be used as a mordant in dyeing.
The mechanism of fluorination by DAST parallels that of sulfur tetrafluoride. Attack of the hydroxyl group of the substrate on sulfur and elimination of hydrogen fluoride lead to an alkoxyaminosulfur difluoride intermediate. Nucleophilic attack by fluoride, either by an S N 1 [5] or S N 2 [6] pathway, leads to the product. Although clean ...
The benefit of transmetalling to zinc it is often more tolerant of other functional groups in the molecule due to the low reactivity which increases selectivity. [15] In the synthesis of Maoecrystal V, a directed ortho metalation gives the initial aryl-lithium species, which is transmetallated to the desired arylzinc compound. The arylzinc ...
Being the conjugate base of a strong acid (nitric acid, pK a = -1.4), nitrate has modest Lewis basicity.Two coordination modes are common: unidentate and bidentate.Often, bidentate nitrate, denoted κ 2-NO 3, is bound unsymmetrically in the sense that one M-O distance is clearly bonding and the other is more weakly interacting. [2]
Over 17,000 pounds of DJ’s Original Boudain sausage links, fresh and frozen, were recalled in three states due to potential foreign matter contamination.
Iron(II) nitrate is the nitrate salt of iron(II). It is commonly encountered as the green hexahydrate, Fe(NO 3) 2 ·6H 2 O, which is a metal aquo complex, however it is not commercially available unlike iron(III) nitrate due to its instability to air. The salt is soluble in water and serves as a ready source of ferrous ions.