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The chemical potential of component i in solution for (left) ideal [incorrectly linearized] and (right) real solutions . Generally the chemical potential is given as a sum of an ideal contribution and an excess contribution: = +,
A ChemFET is a chemically-sensitive field-effect transistor, that is a field-effect transistor used as a sensor for measuring chemical concentrations in solution. [1] When the target analyte concentration changes, the current through the transistor will change accordingly. [2] Here, the analyte solution separates the source and gate electrodes. [3]
COSMO-RS (short for COnductor like Screening MOdel for Real Solvents) [1] [2] [3] is a quantum chemistry based equilibrium thermodynamics method with the purpose of predicting chemical potentials μ in liquids. It processes the screening charge density σ on the surface of molecules to calculate the chemical potential μ of each species in ...
µ is the total chemical potential of electrons, or Fermi level (in semiconductor physics, this quantity is more often denoted E F). The Fermi level of a solid is directly related to the voltage on that solid, as measured with a voltmeter. Conventionally, in band structure plots the Fermi level is taken to be the zero of energy (an arbitrary ...
A compound semiconductor is a semiconductor compound composed of chemical elements of at least two different species. These semiconductors form for example in periodic table groups 13–15 (old groups III–V), for example of elements from the Boron group (old group III, boron, aluminium, gallium, indium) and from group 15 (old group V, nitrogen, phosphorus, arsenic, antimony, bismuth).
When a semiconductor is in thermal equilibrium, the distribution function of the electrons at the energy level of E is presented by a Fermi–Dirac distribution function. In this case the Fermi level is defined as the level in which the probability of occupation of electron at that energy is 1 ⁄ 2. In thermal equilibrium, there is no need to ...
These two examples show that an electrical potential and a chemical potential can both give the same result: A redistribution of the chemical species. Therefore, it makes sense to combine them into a single "potential", the electrochemical potential , which can directly give the net redistribution taking both into account.
An example band-bending diagram is shown in the figure. For convenience, energy is expressed in eV and voltage is expressed in volts, avoiding the need for a factor q for the elementary charge . In the figure, a two-layer structure is shown, consisting of an insulator as left-hand layer and a semiconductor as right-hand layer.