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The concept of internal energy and its relationship to temperature. If a system has a definite temperature, then its total energy has three distinguishable components, termed kinetic energy (energy due to the motion of the system as a whole), potential energy (energy resulting from an externally imposed force field), and internal energy. The ...
Some introductory physics textbooks still define the pressure-temperature relationship as Gay-Lussac's law. [ 6 ] [ 7 ] [ 8 ] Gay-Lussac primarily investigated the relationship between volume and temperature and published it in 1802, but his work did cover some comparison between pressure and temperature. [ 9 ]
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
Conservative temperature is defined to be directly proportional to potential enthalpy. It is rescaled to have the same units as the in-situ temperature: = where = 3989.24495292815 J kg −1 K −1 is a reference value of the specific heat capacity, chosen to be as close as possible to the spatial average of the heat capacity over the entire ocean surface.
For example, a pressure reservoir is a system at a particular pressure, which imposes that pressure upon the system to which it is mechanically connected. The Earth's atmosphere is often used as a pressure reservoir. The ocean can act as temperature reservoir when used to cool power plants.
Entropy cannot be measured directly. The change in entropy with respect to pressure at a constant temperature is the same as the negative change in specific volume with respect to temperature at a constant pressure, for a simple compressible system. Maxwell relations in thermodynamics are often used to derive thermodynamic relations. [2]
The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): = = Here is the thermal expansion coefficient: = is the isothermal compressibility (the inverse of the bulk modulus):
where T denotes the absolute thermodynamic temperature, P the pressure, S the entropy, V the volume, and U the internal energy of the system. In other words, Δ G = 0 {\displaystyle \Delta G=0} is a necessary condition for chemical equilibrium under these conditions (in the absence of an applied voltage).