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Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged.
During this process, surface tension decrease as function of time and finally approach the equilibrium surface tension (σ equilibrium). [3] Such a process is illustrated in figure 1. (Image was reproduced from reference) [2] Figure 1: Migration of surfactant molecules and change of surface tension (σ t1 > σ t2 > σ equilibrium).
This assumption is approximately fulfilled for most known liquids. When plotting the surface tension versus the temperature a fairly straight line can be seen which has a surface tension of zero at the critical temperature. The Eötvös rule also gives a relation of the surface tension behaviour of different liquids in respect to each other: 2.
A classical torsion wire-based du Noüy ring tensiometer. The arrow on the left points to the ring itself. The most common correction factors include Zuidema–Waters correction factors (for liquids with low interfacial tension), Huh–Mason correction factors (which cover a wider range than Zuidema–Waters), and Harkins–Jordan correction factors (more precise than Huh–Mason, while still ...
'drop') is one of the most common methods for measuring surface tension. The principle is to measure the weight of drops of a fluid of interest falling from a capillary glass tube, and thereby calculate the surface tension of the fluid. We can determine the weight of the falling drops by counting them. From it we can determine the surface tension.
The Laplace pressure is the pressure difference between the inside and the outside of a curved surface that forms the boundary between two fluid regions. [1] The pressure difference is caused by the surface tension of the interface between liquid and gas, or between two immiscible liquids.
Liquids 1 and 2 fully wet the surface as shown by their low contact angles, so they should be neglected when first drawing the line of best fit to find the critical liquid surface tension needed to effectively wet the PC surface, γ C, which is simply the x-intercept of the best fit line for the Zisman Plot.
The surface tension between the two liquids (for bubbles: between the fluid and the gas) can then be derived from the shape of the drop at this equilibrium point. A device used for such measurements is called a “spinning drop tensiometer”.