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For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H-15 N or 1 H-13 C dipolar couplings are <5 Hz. [19]
Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
Solid-state 900 MHz (21.1 T [1]) NMR spectrometer at the Canadian National Ultrahigh-field NMR Facility for Solids. Solid-state nuclear magnetic resonance (ssNMR) is a spectroscopy technique used to characterize atomic-level structure and dynamics in solid materials. ssNMR spectra are broader due to nuclear spin interactions which can be categorized as dipolar coupling, chemical shielding ...
In 1958 a study of the yielding of soil based on some Cambridge data of the simple shear apparatus tests, and on much more extensive data of triaxial tests at Imperial College London from research led by Professor Sir Alec Skempton at Imperial College, led to the publication of the critical state concept (Roscoe, Schofield & Wroth 1958).
A USBR soil scientist advances a Giddings Probe direct push soil sampler.. Geotechnical investigations are performed by geotechnical engineers or engineering geologists to obtain information on the physical properties of soil earthworks and foundations for proposed structures and for repair of distress to earthworks and structures caused by subsurface conditions; this type of investigation is ...
Few soil erosion models consider gully erosion, mostly due to difficulties in modelling these large erosional features. Several studies have evaluated the ability of soil erosion models to realistically predict measured rates of erosion, mainly on agricultural landscapes. There is often a wide discrepancy between predicted and observed erosion ...
The interaction was first derived by Enrico Fermi in 1930. [7] A classical derivation of this term is contained in "Classical Electrodynamics" by J. D. Jackson. [8] In short, the classical energy may be written in terms of the energy of one magnetic dipole moment in the magnetic field B(r) of another dipole.
In nuclear chemistry and nuclear physics, J-couplings (also called spin-spin coupling or indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect interaction between two nuclear spins that arises from hyperfine interactions between the nuclei and local electrons. [ 1 ]