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The steady state approximation, [1] occasionally called the stationary-state approximation or Bodenstein's quasi-steady state approximation, involves setting the rate of change of a reaction intermediate in a reaction mechanism equal to zero so that the kinetic equations can be simplified by setting the rate of formation of the intermediate equal to the rate of its destruction.
Steady-state conduction is the form of conduction that happens when the temperature difference(s) driving the conduction are constant, so that (after an equilibration time), the spatial distribution of temperatures (temperature field) in the conducting object does not change any further.
An example of steady state conduction is the heat flow through walls of a warm house on a cold day—inside the house is maintained at a high temperature and, outside, the temperature stays low, so the transfer of heat per unit time stays near a constant rate determined by the insulation in the wall and the spatial distribution of temperature ...
In chemistry, a steady state is a more general situation than dynamic equilibrium. While a dynamic equilibrium occurs when two or more reversible processes occur at the same rate, and such a system can be said to be in a steady state, a system that is in a steady state may not necessarily be in a state of dynamic equilibrium, because some of ...
The steady-state heat equation for a volume that contains a heat source (the inhomogeneous case), is the Poisson's equation: − k ∇ 2 u = q {\displaystyle -k\nabla ^{2}u=q} where u is the temperature , k is the thermal conductivity and q is the rate of heat generation per unit volume.
Non-steady-state methods to measure the thermal conductivity do not require the signal to obtain a constant value. Instead, the signal is studied as a function of time. The advantage of these methods is that they can in general be performed more quickly, since there is no need to wait for a steady-state situation.
The standard method can be used for analyzing radial systems under steady state conditions, starting with the appropriate form of the heat equation, or the alternative method, starting with the appropriate form of Fourier's law. For a hollow cylinder in steady state conditions with no heat generation, the appropriate form of heat equation is [9]
In the study of heat conduction, the Fourier number, is the ratio of time, , to a characteristic time scale for heat diffusion, .This dimensionless group is named in honor of J.B.J. Fourier, who formulated the modern understanding of heat conduction. [1]