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Silane is of practical interest as a precursor to elemental silicon. Silanes with alkyl groups are effective water repellents for mineral surfaces such as concrete and masonry. Silanes with both organic and inorganic attachments are used as coupling agents. They are commonly used to apply coatings to surfaces or as an adhesion promoter. [7]
The plastic industry makes use of certain organic coupling agents, like adhesion promoters, which can thus be manufactured from trimethoxysilane. An example is trimethoxysilylpropyl methacrylate, which is produced by direct addition of trimethoxy silane to the 3-methacryloxypropyl group in the presence of radical scavengers.
– Silicon dioxide layers are the most commonly deposited layers. Freshly deposited layers are highly reactive and can thus serve as adhesion promoting layers for polymer coatings and bondings. Adhesion can be further improved by application of additional silane-based adhesion promoters such as glymo (glycidoxypropyl trimethoxysilane).
Silane SiH 4, the parent. Binary silicon-hydrogen compounds (which are sometimes called silanes also) includes silane itself but also compounds with Si-Si bonds including disilane and longer chains. Silanes with one, two, three, or four Si-H bonds are called hydrosilanes. Silane is again the parent member. Examples: triethylsilane (HSi(C 2 H 5)
Sealant products manufactured with silyl-modified polymers generally have most of the desirable properties of acrylic- or polyurethane-based products, including high opacity, short drying time, and good paint adhesion, as well as some key properties of silicone-based products, including adhesion to a wider range of substrate materials, higher ...
Amino-functional silanes such as (3-aminopropyl)triethoxysilane and epoxy-functional silanes are used for the same purpose. The silane group attaches to the glass substrate via covalent Si-O-Si bond, while the resin reacts with the vinyl-, amino-, or epoxy- group and binds to it.
A common silane used to treat glass surfaces for this application is (3-mercaptopropyl) trimethoxysilane, which increases the number of reactive thiol groups on the surface [11] The nucleic acids can bond to these available thiol groups on the surface of the glass DNA chip after silanization occurs.
Tertiary silanes may also be dehydrogenatively coupled to aromatic rings with the use of the catalyst Tp Me2 Pt(Me) 2 H (Tp Me2 = hydrido tris(3,5-dimethylpyrazolyl)borate). For example, this platinum catalyst can be used to react triethyl silane with benzene to produce phenyltriethylsilane, with the elimination of hydrogen gas.