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The Fermi level does not necessarily correspond to an actual energy level (in an insulator the Fermi level lies in the band gap), nor does it require the existence of a band structure. Nonetheless, the Fermi level is a precisely defined thermodynamic quantity, and differences in Fermi level can be measured simply with a voltmeter.
In the case of a degenerate semiconductor, an electron from the top of the valence band can only be excited into conduction band above the Fermi level (which now lies in conduction band) since all the states below the Fermi level are occupied states. Pauli's exclusion principle forbids excitation into these occupied states. Thus we observe an ...
Thomas–Fermi screening is a theoretical approach to calculate the effects of electric field screening by electrons in a solid. [1] It is a special case of the more general Lindhard theory; in particular, Thomas–Fermi screening is the limit of the Lindhard formula when the wavevector (the reciprocal of the length-scale of interest) is much smaller than the Fermi wavevector, i.e. the long ...
In undoped semiconductors the Fermi level lies in the middle of a forbidden band or band gap between two allowed bands called the valence band and the conduction band. The valence band, immediately below the forbidden band, is normally very nearly completely occupied. The conduction band, above the Fermi level, is normally nearly completely empty.
When a material's Fermi level falls in a bandgap, there is no Fermi surface. Fig. 2: A view of the graphite Fermi surface at the corner H points of the Brillouin zone showing the trigonal symmetry of the electron and hole pockets. Materials with complex crystal structures can have quite intricate Fermi surfaces.
E i: The intrinsic Fermi level may be included in a semiconductor, to show where the Fermi level would have to be for the material to be neutrally doped (i.e., an equal number of mobile electrons and holes). E imp: Impurity energy level. Many defects and dopants add states inside the band gap of a semiconductor or insulator. It can be useful to ...
When the electron dynamics in the bound states just above the Fermi level need to be studied, two-photon excitation in pump-probe setups is used. There, the first photon of low-enough energy is used to excite electrons into unoccupied bands that are still below the energy necessary for photoemission (i.e. between the Fermi and vacuum levels).
Similarly, when a metal is deposited onto a semiconductor (by thermal evaporation, for example), the wavefunction of an electron in the semiconductor must match that of an electron in the metal at the interface. Since the Fermi levels of the two materials must match at the interface, there exists gap states that decay deeper into the semiconductor.