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Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula H 3 P O 4. It is commonly encountered as an 85% aqueous solution, which is a colourless, odourless, and non-volatile syrupy liquid. It is a major industrial ...
The "backbone" of a polyphosphoric acid molecule is a chain of alternating P and O atoms. Each extra orthophosphoric unit that is condensed adds 1 extra H atom, 1 extra P atom, and 3 extra O atoms. The general formula of a polyphosphoric acid is H n+2 P n O 3n+1 or HO[−P(O)(OH)−O−] n H.
Triammonium phosphate can be prepared in the laboratory by treating 85% phosphoric acid with 30% ammonia solution: [citation needed] H 3 PO 4 + 3 NH 3 → (NH 4) 3 PO 4 (NH 4) 3 PO 4 is a colorless, crystalline solid. The solid, which has the odor of ammonia, is readily soluble in water. The salt converts to diammonium hydrogen phosphate (NH 4 ...
Density (near r.t.) white: 1.823 ... [40] 85% of Earth's known reserves are in Morocco with smaller deposits in China, ... (ortho)phosphoric acid: 3: acid, salts Nitrides
Wet-process phosphoric acid is prepared by adding sulfuric acid (H 2 SO 4) to apatite or tricalcium phosphate rock resulting in the following reaction: 3 H 2 SO 4 + Ca 3 (PO 4) 2 + 6 H 2 O ↔ 2 H 3 PO 4 + 3 CaSO 4 •2H 2 O Wet-process acid has to be purified by removing fluorine and other undesirable elements to produce feed-grade phosphoric ...
With a gyromagnetic ratio 40.5% of that for 1 H, 31 P-NMR signals are observed near 202 MHz on an 11.7-Tesla magnet (used for 500 MHz 1 H-NMR measurements). Chemical shifts are typically referenced to 85% phosphoric acid, which is assigned the chemical shift of 0, and appear at positive values (downfield of the standard). [2]
Phase behavior Triple point: 289.8 K (16.7 °C), ? Pa Critical point: 593 K (320 °C), 57.8 bar Eutectic point with water –26.7 °C Std enthalpy change
They can be considered as esters of an unobserved tautomer phosphorous acid, H 3 PO 3, with the simplest example being trimethylphosphite, P(OCH 3) 3. Some phosphites can be considered esters of the dominant tautomer of phosphorous acid (HP(O)(OH) 2). The simplest representative is dimethylphosphite with the formula HP(O)(OCH 3) 2. Both classes ...