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In CPOX (catalytic partial oxidation) the use of a catalyst reduces the required temperature to around 800°C – 900°C. [citation needed] The choice of reforming technique depends on the sulfur content of the fuel being used. CPOX can be employed if the sulfur content is below 50 ppm. A higher sulfur content can poison the catalyst, so the ...
Partial oxidation (POX) is a type of chemical reaction. It occurs when a substoichiometric fuel-air mixture is partially combusted in a reformer, creating a hydrogen-rich syngas which can then be put to further use, for example in a fuel cell. A distinction is made between thermal partial oxidation (TPOX) and catalytic partial oxidation (CPOX).
Syngas is produced by steam reforming or partial oxidation of natural gas or liquid hydrocarbons, or coal gasification. [6] C + H 2 O → CO + H 2 [1] CO + H 2 O → CO 2 + H 2 [1] C + CO 2 → 2CO [1] Steam reforming of methane is an endothermic reaction requiring 206 kJ/mol of methane: CH 4 + H 2 O → CO + 3 H 2
A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. There are multiple types of reformers in development but the most common in industry are autothermal reforming (ATR) and steam methane ...
Steam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is often hydrogen production , although syngas has multiple other uses such as production of ammonia or methanol .
Hydrogen production from natural gas and heavier hydrocarbons is achieved by partial oxidation. A fuel-air or fuel-oxygen mixture is partially combusted, resulting in a hydrogen- and carbon monoxide-rich syngas. More hydrogen and carbon dioxide are then obtained from carbon monoxide (and water) via the water-gas shift reaction. [35]
The sensitivity of catalytic reforming to contamination by sulfur and nitrogen requires hydrotreating the naphtha before it enters the reformer, adding to the cost and complexity of the process. Dehydrogenation, an important component of reforming, is a strongly endothermic reaction, and as such, requires the reactor vessel to be externally heated.
Chemical looping systems can directly be engaged as an effective means for syngas production. Compared to the conventional partial oxidation (POX) or autothermal reforming (ATR) processes, the key advantage of the chemical looping reforming (CLR) process is the elimination of the air separation unit (ASU) for oxygen production. The gaseous fuel ...