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One account of the illness and 1821 death of Napoleon I implicates arsenic poisoning involving wallpaper. [74] Two arsenic pigments have been widely used since their discovery – Paris Green in 1814 and Scheele's Green in 1775. After the toxicity of arsenic became widely known, these chemicals were used less often as pigments and more often as ...
Arsenic (33 As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75 As, is stable; as such, it is considered a monoisotopic element . The longest-lived radioisotope is 73 As with a half-life of 80 days.
Arsenic trioxide should not be mixed or administered in the same infusion with other medications. [92] In pharmaceutical compounding, arsenic trioxide was used in a 1:10 trituration with lactose (Trituratio Acidi arsenicosi 1/10). To prepare the trituration, one part arsenic trioxide is placed in a mortar, and while continuously grinding, nine ...
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
Arsenic biochemistry is the set of biochemical processes that can use arsenic or its compounds, such as arsenate. Arsenic is a moderately abundant element in Earth's crust , and although many arsenic compounds are often considered highly toxic to most life, a wide variety of organoarsenic compounds are produced biologically and various organic ...
A variety of heterocycles containing arsenic(III) are known. These include arsole, the arsenic analogue of pyrrole, and arsabenzene, the arsenic analogue of pyridine. Symmetrical organoarsenic(III) compounds, e.g. trimethylarsine and triphenylarsine, are commonly used as ligands in coordination chemistry. They behave like phosphine ligands, but ...
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]
Arsenic trioxide is an inorganic compound with the formula As 2 O 3. [5] As an industrial chemical, its major uses include the manufacture of wood preservatives, pesticides, and glass. [6] It is sold under the brand name Trisenox among others [2] [3] when used as a medication to treat a type of cancer known as acute promyelocytic leukemia. [7]