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The extremely low coefficient of thermal expansion, about 5.5 × 10 −7 /K (20–320 °C), accounts for its remarkable ability to undergo large, rapid temperature changes without cracking (see thermal shock). Phosphorescence in fused quartz from an extremely intense pulse of UV light in a flashtube, centered at 170 nm
Borosilicate (low expansion, similar to Pyrex, Duran) Glass wool (for thermal insulation) Special optical glass (similar to Lead crystal) Fused silica Germania glass Germanium selenide glass Chemical composition, wt% 74 SiO 2, 13 Na 2 O, 10.5 CaO, 1.3 Al 2 O 3, 0.3 K 2 O, 0.2 SO 3, 0.2 MgO, 0.01 TiO 2, 0.04 Fe 2 O 3
Guitar slide made of borosilicate glass. Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10 −6 K −1 at 20 °C), making them more resistant to thermal shock than any other common glass.
A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
As quoted in an online version of: David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition.CRC Press. Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Physical Properties of the Rare Earth Metals
Borosilicate glasses have fairly low coefficients of thermal expansion (7740 Pyrex CTE is 3.25 × 10 −6 /°C [78] as compared to about 9 × 10 −6 /°C for a typical soda–lime glass [79]). They are, therefore, less subject to stress caused by thermal expansion and thus less vulnerable to cracking from thermal shock.
The expansion coefficient for the glassy state is roughly equivalent to that of the crystalline solid. If slower cooling rates are used, the increased time for structural relaxation (or intermolecular rearrangement) to occur may result in a higher density glass product.
The thermal expansion of the glass and metal must be closely matched so that the seal remains solid as the assembly cools. Thinking for example about a metal wire in a glass bulb sealing, the metal glass contact can break if the coefficients of thermal expansion (CTE) are not well aligned.