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Chlorophyll a contains a magnesium ion encased in a large ring structure known as a chlorin. The chlorin ring is a heterocyclic compound derived from pyrrole. Four nitrogen atoms from the chlorin surround and bind the magnesium atom. The magnesium center uniquely defines the structure as a chlorophyll molecule. [8]
The chlorin ring system features a five-membered carbon ring E is created when one of the propionate groups of the porphyrin is cyclised to the carbon atom linking the original pyrrole rings C and D. A series of chemical steps catalysed by the enzyme Magnesium-protoporphyrin IX monomethyl ester (oxidative) cyclase [ 7 ] gives the overall ...
The most abundant chlorin is the photosynthetic pigment chlorophyll.Chlorophylls have a fifth, ketone-containing ring unlike the chlorins. Diverse chlorophylls exists, such as chlorophyll a, chlorophyll b, chlorophyll d, chlorophyll e, chlorophyll f, and chlorophyll g.
Pyrroles are a five-atom ring with four carbon atoms and one nitrogen atom. Tetrapyrroles are common cofactors in biochemistry and their biosynthesis and degradation feature prominently in the chemistry of life. Some tetrapyrroles form the active core of compounds with crucial biochemical roles in living systems, such as hemoglobin and chlorophyll.
A cyclic compound or ring compound is a compound in which at least some its atoms are connected to form a ring. [1] Rings vary in size from three to many tens or even hundreds of atoms. Examples of ring compounds readily include cases where: all the atoms are carbon (i.e., are carbocycles),
In these two examples, a metal is complexed at the center of a tetrapyrrole macrocycle ring: the metal being iron in the heme group (iron in a porphyrin ring) of hemoglobin, or magnesium complexed in a chlorin-type ring in the case of chlorophyll. The highly conjugated pi-bonding system of the macrocycle ring absorbs visible light.
Chlorophyll is any of several related green pigments found in cyanobacteria and in the chloroplasts of algae and plants. [2] Its name is derived from the Greek words χλωρός (khloros, "pale green") and φύλλον (phyllon, "leaf"). [3] Chlorophyll allows plants to absorb energy from light.
Chlorophyll a is the most common of the six, present in every plant that performs photosynthesis. Each pigment absorbs light more efficiently in a different part of the electromagnetic spectrum. Chlorophyll a absorbs well in the ranges of 400–450 nm and at 650–700 nm; chlorophyll b at 450–500 nm and at 600–650 nm. Xanthophyll absorbs ...