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Extracted humic acid not a single acid; rather, it is a complex mixture of many different acids containing carboxyl and phenolate groups so that the mixture behaves functionally as a dibasic acid or, occasionally, as a tribasic acid. Commercial humic acid used to amend soil is manufactured using these same well established procedures.
When imazaquin is applied to crops its main interaction is with soil humic acids. It was found that the rate at which imazaquin aggregates on soil humic acids was most affected by the environmental pH. Imazaquin has shown greater adsorption at lower pHs. Adsorption is greatest at a pH nearest the pKa of the carboxylic group of imazaquin.
Increasing the soil's pH increases the ability of naturally occurring humic substances to improve infiltration in hydrophobic soils. Humic acid is only water-soluble at a pH greater than 6.5, while fulvic acid is soluble at all pH ranges. Both resident acids have a property that enables them to reduce the surface tension of water when in solution.
The International Humic Substances Society maintains a collection of standard and reference samples of humic and fulvic acids extracted and fractionated from leonardite, river water, a mineral soil, and peat, plus natural organic matter isolated from river water by reverse osmosis, [4] without fractionation. [5]
Soil consists of both mineral (inorganic) and organic components. The organic components can be subdivided into fractions that are soluble, largely humic acids, and insoluble, the humins. Humins make up about 50% of the organic matter in soil. [1]
Fulvic acid is the genus that contains the matter that has the lowest molecular weight, is soluble in acids and alkalis, and is susceptible to microbial action. Humic acid is the genus that contains the intermediate matter that has medial molecular weight, is soluble in alkalis and insoluble in acids, and has some resistance to microbial action.