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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. ...
When a dielectric is placed in an external electric field, its molecules gain electric dipole moment and the dielectric is said to be polarized. Electric polarization of a given dielectric material sample is defined as the quotient of electric dipole moment (a vector quantity, expressed as coulombs*meters (C*m) in SI units) to volume (meters ...
The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1] Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally.
Note that the dipole moments drawn in this diagram represent the shift of the valence electrons as the origin of the charge, which is opposite the direction of the actual electric dipole moment. The bond dipole moment [5] uses the idea of electric dipole moment to measure the polarity of a chemical bond within a molecule. It occurs whenever ...
The linear electric polarizability in isotropic media is defined as the ratio of the induced dipole moment of an atom to the electric field that produces this dipole moment. [ 5 ] Therefore, the dipole moment is:
The electron's electric dipole moment (EDM) must be collinear with the direction of the electron's magnetic moment (spin). [1] Within the Standard Model, such a dipole is predicted to be non-zero but very small, at most 10 −38 e⋅cm, [2] where e stands for the elementary charge.
where μ is the electric dipole moment of the effectively polarized water molecule (2.35 D for the SPC/E model), μ 0 is the dipole moment of an isolated water molecule (1.85 D from experiment), and α i is an isotropic polarizability constant, with a value of 1.608 × 10 −40 F·m 2. Since the charges in the model are constant, this ...
The size of the induced dipole moment is equal to the product of the strength of the external field and the dipole polarizability of ρ. Dipole moment values can be obtained from measurement of the dielectric constant. Some typical gas phase values given with the unit debye are: [7] carbon dioxide: 0; carbon monoxide: 0.112 D; ozone: 0.53 D