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Polychlorotrifluoroethylene (PCTFE or PTFCE) is a thermoplastic chlorofluoropolymer with the molecular formula (CF 2 CClF) n, where n is the number of monomer units in the polymer molecule. It is similar to polytetrafluoroethene (PTFE), except that it is a homopolymer of the monomer chlorotrifluoroethylene (CTFE) instead of tetrafluoroethene.
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. [3] The commonly known brand name of PTFE-based composition is Teflon by Chemours , [ 4 ] a spin-off from DuPont , which originally invented the compound in 1938. [ 4 ]
A fluoropolymer is a fluorocarbon-based polymer with multiple carbon–fluorine bonds. It is characterized by a high resistance to solvents , acids , and bases . The best known fluoropolymer is polytetrafluoroethylene under the brand name "Teflon," trademarked by the DuPont Company.
Chlorotrifluoroethylene (CTFE) is a chlorofluorocarbon with chemical formula CFCl=CF 2.It is commonly used as a refrigerant in cryogenic applications. CTFE has a carbon-carbon double bond and so can be polymerized to form polychlorotrifluoroethylene or copolymerized to produce the plastic ECTFE.
10% PTFE and 15% graphite by weight, SP-211 added to the base resin for the lowest coefficient of friction over a wide range of operating conditions. It also has excellent wear resistance up to 149 °C (300 °F). Typical applications include sliding or linear bearings as well as many wear and friction uses listed above. Example: Vespel SP-211.
PCTFE (polychlorotrifluoroethylene, structural unit: –CF 2 CFCl–) is another important compound. It differs from PTFE by having a quarter of fluorine replaced with chlorines, yet this difference brings even greater hardness, creep resistance, and moisture persistence. [130]
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ECTFE has a continuous usage temperature range between –76°C and +150°C (–105°F to +300°F). It has strong impact resistance and a Young's modulus in the range of 1700 MPa, [5] allowing for self-standing items and pressure piping systems. The polymer maintains high impact strength in cryogenic applications. [6]