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Therefore, to terminate the polymerization, a quenching agent must be added, such as a strong acid to protonate the polymer, or a nucleophile to add an end cap the polymer. If the π-complex is too weakly bound, termination of polymer chains can occur before a quenching agent is added, causing lower molecular weight polymers to form.
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry , analytical ...
Artificial polymer: Man-made polymer that is not a biopolymer. Note 1: Artificial polymer should also be used in the case of chemically modified biopolymers. Note 2: Biochemists are now capable of synthesizing copies of biopolymers that should be named Synthetic biopolymer to make a distinction with true biopolymers.
Living polymerization: A chain polymerization from which chain transfer and chain termination are absent.. Note: In many cases, the rate of chain initiation is fast compared with the rate of chain propagation, so that the number of kinetic-chain carriers is essentially constant throughout the polymerization.
Suspension polymerization is divided into two main types, depending on the morphology of the particles that result. In bead polymerization, the polymer is soluble in its monomer and the result is a smooth, translucent bead. In powder polymerization, the polymer is not soluble in its monomer and the resultant bead will be porous and irregular. [5]
Synthesis of polyurethane from a diisocyanate and a diol. To cap this polymer, chain extenders of either diols or diamines can be added in order to tailor the properties. The mechanical properties of biodegradable polymers can be enhanced with the addition of fillers or other polymers to make a composite, blend, or copolymer.
In polymer chemistry, radical polymerization (RP) is a method of polymerization by which a polymer forms by the successive addition of a radical to building blocks (repeat units).
In polymer chemistry, in situ polymerization is a preparation method that occurs "in the polymerization mixture" and is used to develop polymer nanocomposites from nanoparticles. There are numerous unstable oligomers ( molecules ) which must be synthesized in situ (i.e. in the reaction mixture but cannot be isolated on their own) for use in ...