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Most commercial methods for the synthesis of PAN are based on free radical polymerization of acrylonitrile. [14] In most of the cases, 10% amounts of other vinyl comonomers are also used (1–10%) along with AN depending on the final application. Comonomers include acrylic acid, acrylamide, allyl compounds, and sulfonated styrene. [2]
Therefore, to terminate the polymerization, a quenching agent must be added, such as a strong acid to protonate the polymer, or a nucleophile to add an end cap the polymer. If the π-complex is too weakly bound, termination of polymer chains can occur before a quenching agent is added, causing lower molecular weight polymers to form.
Specific materials and their applications include polymer-protein and polymer-drug conjugates, mediation of enzyme activity, molecular recognition processes and polymeric micelles which can deliver a drug to a specific site in the body. [19] RAFT has also been used to graft polymer chains onto polymeric surfaces, for example, polymeric ...