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Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms. [2]: 1.1 It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot.
Semi-empirical quantum chemistry methods Møller–Plesset perturbation theory Configuration interaction Coupled cluster Multi-configurational self-consistent field Quantum chemistry composite methods Quantum Monte Carlo: Density functional theory; Time-dependent density functional theory Thomas–Fermi model Orbital-free density functional theory
The category of quantum models encompasses a variety of exactly solvable problems in quantum mechanics. Each exactly solvable problem is of interest for several reasons. It provides a test case for methods applicable to other problems. It can be used as a starting point for perturbation theory.
Calculations based on the Bohr–Sommerfeld model were able to accurately explain a number of more complex atomic spectral effects. For example, up to first-order perturbations, the Bohr model and quantum mechanics make the same predictions for the spectral line splitting in the Stark effect. At higher-order perturbations, however, the Bohr ...
Experiments including electromagnetic radiation and matter - such as the photoelectric effect, Compton effect, and spectra of sunlight the due to the unknown element of Helium, the limitation of the Bohr model to Hydrogen, and numerous other reasons, lead to an entirely new mathematical model of matter and light: quantum mechanics. [15]
In quantum optics, the Jaynes–Cummings model (sometimes abbreviated JCM) is a theoretical model that describes the system of a two-level atom interacting with a quantized mode of an optical cavity (or a bosonic field), with or without the presence of light (in the form of a bath of electromagnetic radiation that can cause spontaneous emission ...
The principal quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals. However, the modern theory still requires the principal quantum ...
The quantum harmonic oscillator; The quantum harmonic oscillator with an applied uniform field [1] The Inverse square root potential [2] The periodic potential The particle in a lattice; The particle in a lattice of finite length [3] The Pöschl–Teller potential; The quantum pendulum; The three-dimensional potentials The rotating system The ...