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Its chemical names are based on considering the structure as either an acetyl (methyl-ketone) analog of anisole. Other names It can also be seen as a methyl ether analog of acetophenone . Acetanisole is found naturally in castoreum , the glandular secretion of the beaver .
Structures of the three isomers of tolyl group. In organic chemistry, tolyl groups are functional groups related to toluene. [1] They have the general formula CH 3 C 6 H 4 −R, the change of the relative position of the methyl and the R substituent on the aromatic ring can generate three possible structural isomers 1,2 (ortho), 1,3 (meta), and 1,4 (para).
CH 3 OC 6 H 5 + (CH 3 CO) 2 O → CH 3 OC 6 H 4 C(O)CH 3 + CH 3 CO 2 H. Unlike most acetophenones, but reflecting the influence of the methoxy group, methoxyacetophenone undergoes a second acetylation. Many related reactions have been demonstrated. For example, phosphorus pentasulfide (P 4 S 10) converts anisole to Lawesson's reagent, [(CH 3 OC ...
Pages in category "4-Tolyl compounds" The following 25 pages are in this category, out of 25 total. This list may not reflect recent changes. A. Acrivastine; B.
Tris(o-tolyl)phosphine is an organophosphorus compound with the formula P(C 6 H 4 CH 3) 3. It is a white, water-insoluble solid that is soluble in organic solvents. In solution it slowly converts to the phosphine oxide. As a phosphine ligand, it has a wide cone angle of 194°.
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By replacing the acidic hydrogen on phenol with that of an alkyl group, the toxicity of phenols is also reduced; the LD50 of phenol in rats when administered orally is 317 mg/kg, compared to 3500-4000 mg/kg for anisole, the methyl ether. [9] [10] Furthermore, ethers are significantly more hydrophobic than phenols and can be more easily absorbed ...
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