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Any analyte that can be oxidized or reduced is a candidate for amperometric detection. The simplest form of amperometric detection is single-potential, or direct current (DC), amperometry. A voltage (potential) is applied between two electrodes positioned in the column effluent. The measured current changes as an electroactive analyte is ...
Double-pulsed chronoamperometry waveform showing integrated region for charge determination.. In electrochemistry, chronoamperometry is an analytical technique in which the electric potential of the working electrode is stepped and the resulting current from faradaic processes occurring at the electrode (caused by the potential step) is monitored as a function of time.
"Pulsed amperometric detection of proteins using antibody containing conducting polymers" - Analytica Chimica Acta (1993) [29] "Strain Response From Polypyrrole Actuators Under Load" - Advanced Functional Materials (2002) [30] "Use of Ionic Liquids for p-Conjugated Polymer Electrochemical Devices" - Science (2002) [31]
In LET eddy currents are generated by providing the relative motion between the conductor under test and a permanent magnet(see figure). If the magnet is passing by a defect, the Lorentz force acting on it shows a distortion whose detection is the key for the LET working principle.
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the sample's composition.
Differential pulse voltammetry has these characteristics: 1) reversible reactions have symmetric peaks, and irreversible reactions have asymmetric peaks, 2) the peak potential is equal to E 1/2 r-ΔE in reversible reactions, and the peak current is proportional to the concentration, 3) The detection limit is about 10 −8 M. [citation needed]
Furthermore, in 2009 release of the USP-NF, the United States Pharmacopia made several analyses of ion chromatography available using two techniques: conductivity detection, as well as pulse amperometric detection. Majority of these applications are primarily used for measuring and analyzing residual limits in pharmaceuticals, including ...
A special form of the Pirani gauge is the pulsed Pirani vacuum gauge where the sensor wire is not operated at a constant temperature, but is cyclically heated up to a certain temperature threshold by an increasing voltage ramp. When the threshold is reached, the heating voltage is switched off and the sensor cools down again.