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Recent advances in this technique include the 1D-CSSF (chemical shift selective filter) TOCSY experiment, which produces higher quality spectra and allows coupling constants to be reliably extracted and used to help determine stereochemistry. TOCSY is sometimes called "homonuclear Hartmann–Hahn spectroscopy" (HOHAHA). [12]
Hemispherical electron energy analyzer. A hemispherical electron energy analyzer or hemispherical deflection analyzer is a type of electron energy spectrometer generally used for applications where high energy resolution is needed—different varieties of electron spectroscopy such as angle-resolved photoemission spectroscopy (ARPES), X-ray photoelectron spectroscopy (XPS) and Auger electron ...
Highly anisotropic solids like graphite (quasi-2D) and Bechgaard salts (quasi-1D) show anomalies in spectroscopic measurements that are attributable to the Van Hove singularities. Van Hove singularities play a significant role in understanding optical intensities in single-walled carbon nanotubes (SWNTs) which are also quasi-1D systems. Twisted ...
Absorption spectrum of an aqueous solution of potassium permanganate.The spectrum consists of a series of overlapping lines belonging to a vibronic progression. Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum.
The most direct experimental technique to resolve the electronic structure of crystals in the momentum-energy space (see reciprocal lattice), and, consequently, the Fermi surface, is the angle-resolved photoemission spectroscopy (ARPES). An example of the Fermi surface of superconducting cuprates measured by ARPES is shown in Figure 3.
Luttinger liquid theory describes low energy excitations in a 1D electron gas as bosons. Starting with the free electron Hamiltonian: = † is separated into left and right moving electrons and undergoes linearization with the approximation () over the range :
In imaging spectroscopy (also hyperspectral imaging or spectral imaging) each pixel of an image acquires many bands of light intensity data from the spectrum, instead of just the three bands of the RGB color model. More precisely, it is the simultaneous acquisition of spatially coregistered images in many spectrally contiguous bands.
Brillouin spectroscopy is similar to the more widely known Raman scattering, but probes a lower energy and has a superior energy resolution in order to be able to detect the meV energy of magnons. Ferromagnetic (or antiferromagnetic) resonance instead measures the absorption of microwaves , incident on a magnetic material, by spin waves ...