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"The Children's Story" is a 4,300-word dystopian fiction novelette by James Clavell. It first appeared in Ladies' Home Journal (October 1963 issue) and was printed in book form in 1981. It was adapted by Clavell himself into a thirty-minute short film for television which aired on Mobil Showcase .
Clavell briefly returned to filmmaking and directed a thirty-minute adaptation of his novelette The Children's Story. He was meant to do a sequel to Shōgun but instead wrote a novel about the 1979 revolution in Iran, Whirlwind (1986). [27] Clavell eventually returned to the Shōgun sequel, writing Gai-Jin (1993). This was his last completed novel.
The hydrolysis of the ester or peptide bond proceeds in two steps. First, the acyl part of the substrate (the acid part of an ester or the part of a peptide ending in a carboxyl group) is transferred to the serine, making a new ester or amide bond and releasing the other part of the substrate (the alcohol of an ester or the part of the peptide ...
Unlike acid-catalyzed ester hydrolysis, it is not an equilibrium reaction and proceeds to completion. Hydroxide ion attacks the carbonyl carbon to give a tetrahedral intermediate, which then expels an alkoxide ion. The resulting carboxylic acid quickly protonates the alkoxide ion to give a carboxylate ion and an alcohol. [1]
In organic chemistry, an ortho ester is a functional group containing three alkoxy groups attached to one carbon atom, i.e. with the general formula RC(OR') 3. Orthoesters may be considered as products of exhaustive alkylation of unstable orthocarboxylic acids and it is from these that the name 'ortho ester' is derived.
In the traditional saponification, the triglyceride is treated with lye, which cleaves the ester bonds, releasing fatty acid salts (soaps) and glycerol. In one simplified version, the saponification of stearin gives sodium stearate. C 3 H 5 (O 2 C(CH 2) 16 CH 3) 3 + 3 NaOH → C 3 H 5 (OH) 3 + 3 NaO 2 C(CH 2) 16 CH 3
The new direction for Marks and Kondo's adaptation actually comes straight from Clavell's original story. Instead of a white savior narrative, the series explores what it's like to "show up with ...
[1] [2] In organic chemistry, ether cleavage is an acid catalyzed nucleophilic substitution reaction. Depending on the specific ether, cleavage can follow either S N 1 or S N 2 mechanisms. Distinguishing between both mechanisms requires consideration of inductive and mesomeric effects that could stabilize or destabilize a potential carbocation ...