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Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula H F. ... and subsequent reaction with benzene using HF as catalyst. For example, ...
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water.Solutions of HF are colorless, acidic and highly corrosive.A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature.
The lighter noble gases xenon and krypton can be made to react with fluorine under special conditions, while argon will undergo chemical transformations only with hydrogen fluoride. [18] Nitrogen, with its very stable triple bonds, requires electric discharge and high temperatures to combine with fluorine directly. [19]
Though hydrogen fluoride is normally regarded as an exceptionally weak proton acceptor (though a somewhat better one than the SbF 6 – anion), dissociation of its protonated form, the fluoronium ion H 2 F + to HF and the truly naked H + is still a highly endothermic process (ΔG° = +113 kcal/mol), and imagining the proton in the condensed ...
Fluorination with aminosulfuranes is a chemical reaction that transforms oxidized organic compounds into organofluorine compounds.Aminosulfuranes selectively exchange hydroxyl groups for fluorine, but are also capable of converting carbonyl groups, halides, silyl ethers, and other functionality into organofluorides.
Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride, containing various cations and anions (the simplest being H 2 F + and SbF − 6).This mixture is a superacid stronger than pure sulfuric acid, by many orders of magnitude, according to its Hammett acidity function.
Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...
Elemental fluorine and virtually all fluorine compounds are produced from hydrogen fluoride or its aqueous solution, hydrofluoric acid. Hydrogen fluoride is produced in kilns by the endothermic reaction of fluorite (CaF 2) with sulfuric acid: [169] CaF 2 + H 2 SO 4 → 2 HF(g) + CaSO 4. The gaseous HF can then be absorbed in water or liquefied ...