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The principal quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals. However, the modern theory still requires the principal quantum ...
The maximum number of electrons in any shell is 2n 2, where n is the principal quantum number. The maximum number of electrons in a subshell is equal to 2(2 l + 1), where the azimuthal quantum number l is equal to 0, 1, 2, and 3 for s, p, d, and f subshells, so that the maximum numbers of electrons are 2, 6, 10, and 14 respectively.
The principal quantum number describes the electron shell of an electron. The value of n ranges from 1 to the shell containing the outermost electron of that atom, that is [ 12 ] n = 1 , 2 , … {\displaystyle n=1,2,\ldots }
(typically between 1 eV and 10 3 eV), where R ∞ is the Rydberg constant, Z is the atomic number, n is the principal quantum number, h is the Planck constant, and c is the speed of light. For hydrogen-like atoms (ions) only, the Rydberg levels depend only on the principal quantum number n.
is the principal quantum number of an energy level for the atomic electron transition. Note: Here, n 2 > n 1 {\displaystyle n_{2}>n_{1}} By setting n 1 {\displaystyle n_{1}} to 1 and letting n 2 {\displaystyle n_{2}} run from 2 to infinity, the spectral lines known as the Lyman series converging to 91 nm are obtained, in the same manner:
The Balmer series is characterized by the electron transitioning from n ≥ 3 to n = 2, where n refers to the radial quantum number or principal quantum number of the electron. The transitions are named sequentially by Greek letter: n = 3 to n = 2 is called H-α, 4 to 2 is H-β, 5 to 2 is H-γ, and 6 to 2 is H-δ.
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The orbits in which the electron may travel are shown as grey circles; their radius increases as n 2, where n is the principal quantum number. The 3 → 2 transition depicted here produces the first line of the Balmer series, and for hydrogen (Z = 1) it results in a photon of wavelength 656 nm (red light).