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Thermoplastic polyurethane (TPU) is any of a class of polyurethane plastics with many properties, including elasticity, transparency, and resistance to oil, grease, and abrasion. Technically, they are thermoplastic elastomers consisting of linear segmented block copolymers composed of hard and soft segments.
Thermoplastic elastomers show advantages typical of both rubbery materials and plastic materials. The benefit of using thermoplastic elastomers is the ability to stretch to moderate elongations and return to its near original shape creating a longer life and better physical range than other materials.
Compared to processing rubber, thermoplastic processing of TPV can deliver shorter cycle times, higher parts output per hour, and the reuse of scrap produced during processing. These attributes can result in cost reduction, less tooling/machinery, lower scrap costs, and optimization of material logistic costs compared to rubber.
Polyurethane synthesis, wherein the urethane groups −NH−(C=O)−O− link the molecular units A kitchen sponge made of polyurethane foam . Polyurethane (/ ˌ p ɒ l i ˈ jʊər ə ˌ θ eɪ n,-j ʊəˈr ɛ θ eɪ n /; [1] often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links.
This is the reason such a material is called a thermoplastic elastomer (TPE). The polystyrene blocks form domains of nanometre size in the microstructure, and they stabilize the form of the molded material. Depending on the rubber-to-polystyrene ratio in the material, the polystyrene domains can be spherical or form cylinders or lamellae. The ...
Elastomers are usually thermosets (requiring vulcanization) but may also be thermoplastic (see thermoplastic elastomer). The long polymer chains cross-link during curing (i.e., vulcanizing). The molecular structure of elastomers can be imagined as a 'spaghetti and meatball' structure, with the meatballs signifying cross-links.
Examples include Viton rubber, EPDM and butyl rubber. A new class of synthetic rubber is the thermoplastic elastomers which can be moulded easily unlike conventional natural rubber vulcanized rubber. Their structure is stabilized by cross-linking by crystallites in the case of polyurethanes or by amorphous domains in the case of SBS block ...
Polylactic acid (polylactide) is a compostable thermoplastic aliphatic polyester derived from renewable resources, such as corn starch (in the United States), sugar beet pulp (in Europe), tapioca roots, chips or starch (mostly in Asia), or sugarcane. It is the most common material used for 3D printing with fused deposition modeling (FDM ...