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The most commonly used alcohol is methanol, producing fatty acid methyl esters (FAME). When ethanol is used fatty acid ethyl esters (FAEE) are created. Other alcohols used for the production of biodiesel include butanol and isopropanol. Fatty acid ethyl esters are biomarkers for the consumption of ethanol (alcoholic beverages). [1] [2] [3]
In 1939, Cantor, who patented a production route of sucrose fatty acid esters from starch factory by-products, claimed that the products could be used as emulsifying agents or fats. The classical esterification was used with a mixture of pyridine and either chloroform or carbontetrachloride as a solvent.
An example of an ester formation is the substitution reaction between a carboxylic acid (R−C(=O)−OH) and an alcohol (R'OH), forming an ester (R−C(=O)−O−R'), where R and R′ are organyl groups, or H in the case of esters of formic acid. Glycerides, which are fatty acid esters of glycerol, are important esters in biology, being one of ...
Monoglycerides are primarily used as surfactants, usually in the form of emulsifiers.Together with diglycerides, monoglycerides are commonly added to commercial food products in small quantities as "E471" (s.a. Mono- and diglycerides of fatty acids), which helps to prevent mixtures of oils and water from separating.
Diglyceride, in this example with a saturated fatty acid residue (highlighted blue) and an unsaturated fatty acid residue (highlighted green). Mono- and diglycerides of fatty acids ( E 471 ) are a naturally occurring class of food additive composed of diglycerides and monoglycerides used as an emulsifier in foods such as infant formula, fresh ...
The fatty acid or fatty esters are susceptible to hydrogenation converts unsaturated fatty acids into saturated fatty acids. [1] The acids or esters can also be reduced to the fatty alcohols. For some applications, fatty acids are converted to fatty nitriles. Hydrogenated of these nitriles gives fatty amines, which have a variety of ...
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The hydroxide anion adds to the carbonyl group of the ester. The immediate product is called an orthoester. Saponification part I. Expulsion of the alkoxide generates a carboxylic acid: Saponification part II. The alkoxide ion is a strong base so the proton is transferred from the carboxylic acid to the alkoxide ion, creating an alcohol:
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