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Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid.Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas.
It is an aqueous solution of hydrogen iodide with the chemical formula H I. It is a strong acid, in which hydrogen iodide is ionized completely in an aqueous solution. Concentrated aqueous solutions of hydrogen iodide are usually 48% to 57% HI by mass. [2] An oxidized solution of hydriodic acid.
Aqueous hydrogen iodide is known as hydroiodic acid, which is a strong acid. Hydrogen iodide is exceptionally soluble in water: one litre of water will dissolve 425 litres of hydrogen iodide, and the saturated solution has only four water molecules per molecule of hydrogen iodide. [6]
Aqueous hydrogen iodide is known as hydroiodic acid, which is a strong acid. Hydrogen iodide is exceptionally soluble in water: one litre of water will dissolve 425 litres of hydrogen iodide, and the saturated solution has only four water molecules per molecule of hydrogen iodide. [49]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
It forms when an aqueous solution of iodine is treated with mercuric or silver salts. It rapidly decomposes by disproportionation: [2] 5 HIO → HIO 3 + 2 I 2 + 2 H 2 O. Hypoiodous acid is a weak acid with a pK a of about 11. The conjugate base is hypoiodite (IO −). Salts of this anion can be prepared by treating iodine with alkali hydroxides.
Iodic acid crystallises from acidic solution as orthorhombic α-HIO 3 in space group P2 1 2 1 2 1. The structure consists of pyramidal molecules linked by hydrogen bonding and intermolecular iodine-oxygen interactions. The I=O bond lengths are 1.81 Å while the I–OH distance is 1.89 Å.
The first such compound was synthesised in 1894, via the silver hydroxide-catalyzed coupling of two aryl iodides (the Meyer–Hartmann reaction): [19] [20] [21] Alternatively, the iodane may be formed in situ: an aryl iodide is oxidized to an aryliodine(III) compound (such as ArIO), followed by a ligand exchange.