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Strictly speaking, the bulk modulus is a thermodynamic quantity, and in order to specify a bulk modulus it is necessary to specify how the pressure varies during compression: constant- temperature (isothermal ), constant- entropy (isentropic ), and other variations are possible. Such distinctions are especially relevant for gases.
Thermodynamics. In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility[1] or, if the temperature is held constant, the isothermal compressibility[2]) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.
The third-order Birch–Murnaghan isothermal equation of state is given by = [() / /] {+ (′) [() /]}. where P is the pressure, V 0 is the reference volume, V is the deformed volume, B 0 is the bulk modulus, and B 0 ' is the derivative of the bulk modulus with respect to pressure. The bulk modulus and its derivative are usually obtained from ...
In 1895, [3] [4] the original isothermal Tait equation was replaced by Tammann with an equation of the form = = (+) where is the isothermal mixed bulk modulus. This above equation is popularly known as the Tait equation.
At high P-T, the pressure for the ideal gas is calculated by the force divided by the area, while the pressure for the solid is calculated from bulk modulus (K, or B) and volume at room temperature, or from Eq (1) at high P-T. A pressure gauge's bulk modulus is known, and its thermal equation of state is well known.
The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): = = Here is the thermal expansion coefficient: = is the isothermal compressibility (the inverse of the bulk modulus):
The Rose–Vinet equation of state is a set of equations used to describe the equation of state of solid objects. It is a modification of the Birch–Murnaghan equation of state. [1][2] The initial paper discusses how the equation only depends on four inputs: the isothermal bulk modulus , the derivative of bulk modulus with respect to pressure ...
Some formulations for the Grüneisen parameter include: = = = = = ( ) where V is volume, and are the principal (i.e. per-mass) heat capacities at constant pressure and volume, E is energy, S is entropy, α is the volume thermal expansion coefficient, and are the adiabatic and isothermal bulk moduli, is the speed of sound in the medium ...