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Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
Magnetic optical rotation is known as the Faraday effect, and its wavelength dependence is known as magnetic optical rotatory dispersion. In regions of absorption, magnetic circular dichroism is observable.
Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation (α) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ([α]) for the enantiopure compound is known.
The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), [1] is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation.
A simple polarimeter to measure this rotation consists of a long tube with flat glass ends, into which the sample is placed. At each end of the tube is a Nicol prism or other polarizer. Light is shone through the tube, and the prism at the other end, attached to an eye-piece, is rotated to arrive at the region of complete brightness or that of ...
The specific rotation [] is a physical property and defined as the optical rotation α at a path length l of 1 dm, a concentration c of 10 g/L, a temperature T (usually 20 °C) and a light wavelength λ (usually sodium D line at 589.3 nm): [4]
Kerr rotation and Kerr ellipticity are changes in the polarization of incident light which comes in contact with a gyromagnetic material. Kerr rotation is a rotation in the plane of polarization of transmitted light, and Kerr ellipticity is the ratio of the major to minor axis of the ellipse traced out by elliptically polarized light on the plane through which it propagates.
The observed rotation of the sample is the weighted sum of the optical rotation of each anomer weighted by the amount of that anomer present. Therefore, one can use a polarimeter to measure the rotation of a sample and then calculate the ratio of the two anomers present from the enantiomeric excess, as long as one knows the rotation of each pure anomer.