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Another type of binary phase diagram is a boiling-point diagram for a mixture of two components, i. e. chemical compounds. For two particular volatile components at a certain pressure such as atmospheric pressure , a boiling-point diagram shows what vapor (gas) compositions are in equilibrium with given liquid compositions depending on temperature.
In the phase diagram, we can notice that the top point D of the phase diagram is the congruent melting point of the compound AB because the solid and liquid phases now have the same composition. Evidently, at this temperature , the two-component system has become a one-component system because both solid and liquid phases contains only the ...
For pure elements or compounds, e.g. pure copper, pure water, etc. the liquidus and solidus are at the same temperature, and the term melting point may be used. There are also some mixtures which melt at a particular temperature, known as congruent melting. One example is eutectic mixture. In a eutectic system, there is particular mixing ratio ...
The following table gives the crystalline structure of the most thermodynamically stable form(s) for elements that are solid at standard temperature and pressure. Each element is shaded by a color representing its respective Bravais lattice, except that all orthorhombic lattices are grouped together.
Transition temperatures for the constituent elements have dashes ----- in the first column in a blank row, such as at 922 K, the melting point of Mg. Transition temperatures for the substance have two blank rows with dashes, and a center row with the defined transition and the enthalpy change, such as the melting point of MgCl 2 at 980 K. The ...
The melting and boiling points of iron, along with its enthalpy of atomization, are lower than those of the earlier group 3d elements from scandium to chromium, showing the lessened contribution of the 3d electrons to metallic bonding as they are attracted more and more into the inert core by the nucleus; [19] however, they are higher than the ...
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa.
The Gmelin rare earths handbook lists 1522 °C and 1550 °C as two melting points given in the literature, the most recent reference [Handbook on the chemistry and physics of rare earths, vol.12 (1989)] is given with 1529 °C.