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Manganese(II) sulfide is a chemical compound of manganese and sulfur. It occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and recently found browneite (isometric, with sphalerite-type structure, extremely rare, known only from a meteorite).
Organomanganese chemistry is the chemistry of organometallic compounds containing a carbon to manganese chemical bond.In a 2009 review, Cahiez et al. argued that as manganese is cheap and benign (only iron performs better in these aspects), organomanganese compounds have potential as chemical reagents, although currently they are not widely used as such despite extensive research.
Manganese(II) sulfate usually refers to the inorganic compound with the formula MnSO 4 ·H 2 O. This pale pink deliquescent solid is a commercially significant manganese(II) salt. Approximately 260,000 tonnes of manganese(II) sulfate were produced worldwide in 2005. It is the precursor to manganese metal and many other chemical compounds.
Manganese is a key component of low-cost stainless steel. [75] [76] Often ferromanganese (usually about 80% manganese) is the intermediate in modern processes. Small amounts of manganese improve the workability of steel at high temperatures by forming a high-melting sulfide and preventing the formation of a liquid iron sulfide at the grain ...
The pK a of HMn(CO) 5 in water is 7.1. [8] It is thus comparable to hydrogen sulfide, a common inorganic acid, in its acidity.. A common reaction involving HMn(CO) 5 is substitution of the CO ligands by organophosphines, as occurs both thermally and photochemically.
Manganese-mediated couplings have been used for the synthesis of hydrocarbon natural products, such as pheromones. A synthesis of queen bee pheromone uses the intermolecular coupling of acetone and an ω-alkenyl acetate en route to the target. [18] (11) Lactonization is a key step in the synthesis of tomato pinworm sex pheromone.
The reagent is an alkaline solution of potassium permanganate. Reaction with double or triple bonds (R 2 C=CR 2 or R−C≡C−R) causes the color to fade from purplish-pink to brown. Aldehydes and formic acid (and formates) also give a positive test. [43] The test is antiquated. Baeyer's reagent reaction
The Eschenmoser sulfide contraction is an organic reaction first described by Albert Eschenmoser for the synthesis of 1,3-dicarbonyl compounds from a thioester. [1] [2] [3] The method requires a base and a tertiary phosphine. The method is of some relevance to organic chemistry and has been notably applied in the vitamin B 12 total synthesis.