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In the nitrogen cycle, atmospheric nitrogen gas is converted by plants into usable forms such as ammonia and nitrates through the process of nitrogen fixation. These compounds can be used by other organisms, and nitrogen is returned to the atmosphere through denitrification and other processes.
The N value in NPK labels represents actual percentage of nitrogen element by weight, so it does not need to be converted. So, for example, an 18−51−20 fertilizer contains by weight 18% elemental nitrogen, 0.436 × 51 = 22% elemental phosphorus, and; 0.83 × 20 = 17% elemental potassium.