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Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
A perovskite is a crystalline material of formula ABX 3 with a crystal structure similar to that of the mineral perovskite, this latter consisting of calcium titanium oxide (CaTiO 3). [2] The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856).
Ruddlesden-Popper (RP) phases are a type of perovskite structure that consists of two-dimensional perovskite-like slabs interleaved with cations.The general formula of an RP phase is A n+1 B n X 3n+1, where A and B are cations, X is an anion (e.g., oxygen), and n is the number of octahedral layers in the perovskite-like stack. [1]
If the B-X-B angle deviates too far from 180°, phase transitions towards non-luminescent or all-together non-perovskite phases can occur. [121] [122] If the B-X-B angle does not deviate very far from 180°, the overall structure of the perovskite remains as a 3D network of interconnected octahedra, but the optical properties may change.
The typical perovskite structure is represented by the general formula ABX 3, where A and B are cations and X is an anion. When the anion is the ( divalent ) oxide ion, A and B cations can have charges 1 and 5, respectively, 2 and 4, respectively, or 3 and 3, respectively.
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Perovskite light-emitting diodes (PeLEDs) are candidates for display and lighting technologies. Researchers have shown interest in perovskite light-emitting diodes (PeLEDs) owing to their capacity for emitting light with narrow bandwidth , adjustable spectrum , ability to deliver high color purity, and solution fabrication.
Silicate perovskite is either (Mg,Fe)SiO 3 (the magnesium end-member is called bridgmanite [1]) or CaSiO 3 (calcium silicate known as davemaoite) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle , between about 670 and 2,700 km (420 and 1,680 mi ...