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In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade , [ 1 ] and were further developed by others including Michael Mingos ; [ 2 ] they are ...
Kenneth Wade was born in Sleaford on 13 October 1932, the second son of Harry Kennington Wade and his wife, Anna Elizabeth Wade. He was educated at Carre's Grammar School, [2] and graduated from the University of Nottingham as the first PhD student (1954–1957) of Norman Greenwood, [3] [4] and Cornell University.
The simplest alkene, ethylene (C 2 H 4) (or "ethene" in the IUPAC nomenclature) is the organic compound produced on the largest scale industrially. [ 5 ] Aromatic compounds are often drawn as cyclic alkenes, however their structure and properties are sufficiently distinct that they are not classified as alkenes or olefins. [ 3 ]
In chemistry, the Jemmis mno rules represent a unified rule for predicting and systematizing structures of compounds, usually clusters.The rules involve electron counting. They were formulated by E. D. Jemmis to explain the structures of condensed polyhedral boranes such as B 20 H 16, which are obtained by condensing polyhedral boranes by sharing a triangular face, an edge, a single vertex, or ...
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. [1]
The Oxford Chemistry Primers are a series of short texts providing accounts of a range of essential topics in chemistry and chemical engineering written for undergraduate study. The first primer Organic Synthesis: The Roles of Boron and Silicon was published by Oxford University Press in 1991. [ 1 ]
For organic compounds containing heteroatoms (other than C and H), the list of unsaturated groups is long but some common types are: carbonyl , e.g. ketones , aldehydes , esters , carboxylic acids (unsaturated) vs alcohol or ether (saturated)
The Corey–House synthesis (also called the Corey–Posner–Whitesides–House reaction and other permutations) is an organic reaction that involves the reaction of a lithium diorganylcuprate with an organic halide or pseudohalide (′) to form a new alkane, as well as an ill-defined organocopper species and lithium (pseudo)halide as byproducts.