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Electro-oxidation (EO or EOx), also known as anodic oxidation or electrochemical oxidation (EC), is a technique used for wastewater treatment, mainly for industrial effluents, and is a type of advanced oxidation process (AOP). [1] The most general layout comprises two electrodes, operating as anode and cathode, connected to a power source.
This process occurs naturally in plants photosystem II to provide protons and electrons for the photosynthesis process and release oxygen to the atmosphere, [1] as well as in some electrowinning processes. [2] Since hydrogen can be used as an alternative clean burning fuel, there has been a need to split water efficiently.
Although oxidation processes involving ·OH have been in use since late 19th century (such as Fenton's reagent, which was used as an analytical reagent at that time), the utilization of such oxidative species in water treatment did not receive adequate attention until Glaze et al. [1] suggested the possible generation of ·OH "in sufficient ...
Electrocoagulation (EC) is a technique used for wastewater treatment, wash water treatment, industrially processed water, and medical treatment. Electrocoagulation has become a rapidly growing area of wastewater treatment due to its ability to remove contaminants that are generally more difficult to remove by filtration or chemical treatment systems, such as emulsified oil, total petroleum ...
The electrochemical mechanisms of electrocatalytic processes are a common research subject for various fields of chemistry and associated sciences. This is important to the development of water oxidation and fuel cells catalysts. For example, half the water oxidation reaction is the reduction of protons to hydrogen, the subsequent half reaction.
In 1960 the concept of electrochemical demineralization of water was reported by Blair and Murphy. [9] In that study, it was assumed that ions were removed by electrochemical reactions with specific chemical groups on the carbon particles in the electrodes. In 1968 the commercial relevance and long term operation of CDI was demonstrated by Reid ...
The process involves adsorption of organic compounds in the wastewater by the microbial slime layer, diffusion of air into the slime layer to provide the oxygen required for the biochemical oxidation of the organic compounds. The end products include carbon dioxide gas, water and other products of the oxidation. As the slime layer thickens, it ...
Electro precipitation is the removal of heavy metal ions, charged colloids, emulsions and microorganisms by passing direct electric current (introduced via parallel plates constructed of various metals that are selected to optimize the removal process) through contaminated water.