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Case-hardening or carburization is the process of introducing carbon to the surface of a low-carbon iron, or more commonly a low-carbon steel object, in order to harden the surface. Iron which has a carbon content greater than ~0.02% is known as steel .
Frequently, the term "hardening" is associated with tempered steel. Both processes are used hand in hand when hardening steel. The two part process begins with hardening the steel so that it becomes hard and does not wear over time. However, very often, this process leaves the steel very brittle and susceptible to breaking during use.
A few typical hardening agents include carbon monoxide gas (CO), sodium cyanide and barium carbonate, or hardwood charcoal. In gas carburizing, carbon is given off by propane or natural gas . In liquid carburizing, the carbon is derived from a molten salt composed mainly of sodium cyanide (NaCN) and barium chloride (BaCl 2 ).
Krupp armour was a type of steel naval armour used in the construction of capital ships starting shortly before the end of the nineteenth century. It was developed by Germany's Krupp Arms Works in 1893 and quickly replaced Harvey armour as the primary method of protecting naval ships, before itself being supplanted by the improved Krupp ...
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Case hardening processes harden only the exterior of the steel part, creating a hard, wear-resistant skin (the "case") but preserving a tough and ductile interior. Carbon steels are not very hardenable meaning they can not be hardened throughout thick sections. Alloy steels have a better hardenability, so they can be through-hardened and do not ...
In solution hardening, the alloying element does not precipitate from solution. Precipitation hardening (also called age hardening ) is a process where a second phase that begins in solid solution with the matrix metal is precipitated out of solution with the metal as it is quenched, leaving particles of that phase distributed throughout to ...
Carbonitriding alters only the top layers of the workpiece; and does not deposit an additional layer, so the process does not significantly alter the dimensions of the part. Maximum case depth is typically restricted to 0.75 mm; case depths greater than this take too long to diffuse to be economical.