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The haloalkanes (also known as halogenoalkanes or alkyl halides) are alkanes containing one or more halogen substituents. [1] They are a subset of the general class of halocarbons , although the distinction is not often made.
By reaction with tertiary amines, long-chain alkyl bromides such as 1-bromododecane, give quaternary ammonium salts, which are used as phase transfer catalysts. [ 9 ] With Michael acceptors the addition is also anti-Markovnikov because now a nucleophilic X − reacts in a nucleophilic conjugate addition for example in the reaction of HCl with ...
Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic or aromatic. Detailed understanding of a reaction type helps to ...
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In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...
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