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The main polycarbonate material is produced by the reaction of bisphenol A (BPA) and phosgene COCl 2. The overall reaction can be written as follows: The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A. [6] (HOC 6 H 4) 2 CMe 2 + 2 NaOH → Na 2 (OC 6 ...
The type I reaction dominates, which cause chain scission at the carbonyl unit to give a range of products. [1] [38] Type II Norrish reactions are less common but give rise to acetaldehyde by way of vinyl alcohol esters. [36] This has an exceedingly low odour and taste threshold and can cause an off-taste in bottled water. [39]
Supercritical water has a density between that of water vapor and liquid at standard conditions, and exhibits high gas-like diffusion rates along with high liquid-like collision rates. In addition, the behavior of water as a solvent is altered (in comparison to that of subcritical liquid water) - it behaves much less like a polar solvent.
Carbonate esters can be converted to other carbonates by transesterification. A more nucleophilic alcohol will displace a less nucleophilic alcohol. In other words, aliphatic alcohols will displace phenols from aryl carbonates. If the departing alcohol is more volatile, the equilibrium may be driven by distilling that off. [2] [3]
The refractory compounds are thus converted into reaction intermediates and, ultimately, into water and CO 2 by complete mineralization. [ 2 ] Electro-oxidation has recently grown in popularity thanks to its ease of set-up and effectiveness in treating harmful and recalcitrant organic pollutants, which are typically difficult to degrade with ...
FRP tanks and vessels designed as per BS 4994 are widely used in the chemical industry in the following sectors: chlor-alkali manufacturers, fertilizer, wood pulp and paper, metal extraction, refining, electroplating, brine, vinegar, food processing, and in air pollution control equipment, especially at municipal waste water treatment plants and water treatment plants.
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