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In oxygenic photosynthesis, water (H 2 O) serves as a substrate for photolysis resulting in the generation of diatomic oxygen (O 2). This is the process which returns oxygen to Earth's atmosphere. Photolysis of water occurs in the thylakoids of cyanobacteria and the chloroplasts of green algae and plants. [3]
Hill's finding was that the origin of oxygen in photosynthesis is water (H 2 O) not carbon dioxide (CO 2) as previously believed. Hill's observation of chloroplasts in dark conditions and in the absence of CO 2 , showed that the artificial electron acceptor was oxidized but not reduced, terminating the process, but without production of oxygen ...
For instance, although cis-stilbene is "uphill" from trans-stilbene in a thermodynamic sense, irradiation of trans-stilbene results in a mixture that is predominantly the cis isomer. [2] As an extreme example, irradiation of benzene at 237 to 254 nm results in formation of benzvalene , an isomer of benzene that is 71 kcal/mol higher in energy ...
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
The energy of P680 + is used in two steps to split a water molecule into 2H + + 1/2 O 2 + 2e-(photolysis or light-splitting). An electron from the water molecule reduces P680 + back to P680, while the H + and oxygen are released.
This process occurs naturally in plants photosystem II to provide protons and electrons for the photosynthesis process and release oxygen to the atmosphere, [1] as well as in some electrowinning processes. [2] Since hydrogen can be used as an alternative clean burning fuel, there has been a need to split water efficiently.
Light-dependent reactions of photosynthesis at the thylakoid membrane. Light-dependent reactions are certain photochemical reactions involved in photosynthesis, the main process by which plants acquire energy. There are two light dependent reactions: the first occurs at photosystem II (PSII) and the second occurs at photosystem I (PSI).
S 4 reacts with water producing free oxygen: 2 H 2 O → O 2 + 4 H + + 4 e −. This conversion resets the catalyst to the S 0 state. The active site of the OEC consists of a cluster of manganese and calcium with the formula Mn 4 Ca 1 O x Cl 1–2 (HCO 3) y. This cluster is bound to D 1 and CP 43 subunits and stabilized by peripheral membrane ...