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Absorptions bands in the Earth's atmosphere created by greenhouse gases and the resulting effects on transmitted radiation.. In spectroscopy, an absorption band is a range of wavelengths, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance.
Schematic representation of the absorption line shape of an electronic excitation. The narrow component at the frequency ω′ is the zero-phonon line and the broader feature is the phonon sideband. In emission, the relative positions of the two components are mirrored about the center of the zero-phonon line at ω′.
Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field.
According to the description of an atom interacting with the electromagnetic field, the absorption of light by the atom depends on the frequency of the incident photons. More precisely, the absorption is characterized by a Lorentzian of width Γ/2 (for reference, Γ ≈ 2π × 6 MHz for common rubidium D-line transitions [ 2 ] ).
The individual absorption spectra of major greenhouse gases plus Rayleigh scattering are shown in the lower panel. [1] An atmospheric window is a region of the electromagnetic spectrum that can pass through the atmosphere of Earth. The optical, infrared and radio windows comprise the three main atmospheric windows. [2]
Absorption spectrum of an aqueous solution of potassium permanganate.The spectrum consists of a series of overlapping lines belonging to a vibronic progression. Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum.
The absorption intensity is weaker than for the fundamental vibrations, but this is not important as longer path-length cuvettes can be used. The absorption band at 698 nm (14300 cm −1) is a 3rd overtone (n=4). It tails off onto the visible region and is responsible for the intrinsic blue color of water.
In the physical sciences, the spectrum of a physical quantity (such as energy) may be called continuous if it is non-zero over the whole spectrum domain (such as frequency or wavelength) or discrete if it attains non-zero values only in a discrete set over the independent variable, with band gaps between pairs of spectral bands or spectral ...